9/9/2023 0 Comments Boiling point of hydrogen![]() Hydrogen chloride can also be prepared by the hydrolysis of certain reactive chloride compounds such as phosphorus chlorides, thionyl chloride ( SOCl 2), and acyl chlorides. Provided there is NaCl remaining in the generator and it is heated above 200 ☌, the reaction proceeds further:įor such generators to function, the reagents should be dry. This reaction occurs at room temperature. Alternatively, HCl can be generated by the reaction of sulfuric acid with sodium chloride: NaCl + H 2SO 4 → NaHSO 4 + HCl Small amounts of hydrogen chloride for laboratory use can be generated in an HCl generator by dehydrating hydrochloric acid with either sulfuric acid or anhydrous calcium chloride. The resulting hydrogen chloride is either reused directly or absorbed in water, resulting in hydrochloric acid of technical or industrial grade. RH + Cl 2 → RCl + HCl RCl + HF → RF + HCl Fluorination is a subsequent chlorine-replacement reaction, producing again hydrogen chloride: ![]() In the chemical reactions, hydrogen atoms on the hydrocarbon are replaced by chlorine atoms, whereupon the released hydrogen atom recombines with the spare atom from the chlorine molecule, forming hydrogen chloride. Often this production of hydrochloric acid is integrated with captive use of it on-site. The industrial production of hydrogen chloride is often integrated with the formation of chlorinated and fluorinated organic compounds, e.g., Teflon, Freon, and other CFCs, as well as chloroacetic acid and PVC. The reaction can also be triggered by blue light. This reaction can give a very pure product, e.g. The resulting hydrogen chloride gas is absorbed in deionized water, resulting in chemically pure hydrochloric acid. Hydrogen chloride is produced by combining chlorine and hydrogen:Īs the reaction is exothermic, the installation is called an HCl oven or HCl burner. While the spring constants are nearly identical, the disparate reduced masses of H 35Cl and H 37Cl cause measurable differences in the rotational energy, thus doublets are observed on close inspection of each absorption line, weighted in the same ratio of 3:1. Naturally abundant chlorine consists of two isotopes, 35Cl and 37Cl, in a ratio of approximately 3:1. The latter can even be made of quartz as the HCl absorption lies in a window of transparency for this material. However, the vibrational energy of HCl molecule places its absorptions within the infrared region, allowing a spectrum showing the rovibrational transitions of this molecule to be easily collected using an infrared spectrometer with a gas cell. The value of the rotational constant B is much smaller than the vibrational one ν o, such that a much smaller amount of energy is required to rotate the molecule for a typical molecule, this lies within the microwave region. Including anharmonicity the vibrational energy can be written as.Į v = h ν e ( v + 1 2 ) + h x e ν e ( v + 1 2 ) 2 At room temperature, almost all molecules are in the ground vibrational state v = 0. The infrared spectrum of gaseous hydrogen chloride, shown on the left, consists of a number of sharp absorption lines grouped around 2886 cm −1 (wavelength ~3.47 µm). One doublet in the IR spectrum resulting from the isotopic composition of chlorine Hydrogen chloride can protonate molecules or ions and can also serve as an acid- catalyst for chemical reactions where anhydrous (water-free) conditions are desired.īecause of its acidic nature, hydrogen chloride is a corrosive substance, particularly in the presence of moisture. For example, hydrogen chloride can dissolve in certain other solvents such as methanol: Even in the absence of water, hydrogen chloride can still act as an acid. The acid dissociation or ionization constant, K a, is large, which means HCl dissociates or ionizes practically completely in water. The resulting solution is called hydrochloric acid and is a strong acid. Upon contact, H 2O and HCl combine to form hydronium cations + and chloride anions Cl − through a reversible chemical reaction: In part because of its high polarity, HCl is very soluble in water (and in other polar solvents). ![]() Consequently, the molecule has a large dipole moment with a negative partial charge (δ−) at the chlorine atom and a positive partial charge (δ+) at the hydrogen atom. The chlorine atom is much more electronegative than the hydrogen atom, which makes this bond polar. Hydrogen chloride is a diatomic molecule, consisting of a hydrogen atom H and a chlorine atom Cl connected by a polar covalent bond. Hydrochloric acid fumes turning pH paper red showing that the fumes are acidic
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9/9/2023 0 Comments Dying light vs dead island
9/9/2023 0 Comments Best iantivirus suiteIf you have Macs and Android devices to cover in addition to Windows 10 machines, McAfee AntiVirus Plus can meet your needs at a bargain rate – $60 covers 10 devices. Both give you access to an unlimited password manager and Standard adds an unlimited VPN and dark web personal information monitoring. If you have more money to spend and only a single PC to protect, you might want to consider Norton AntiVirus Plus or Norton 360 Standard. The best bang for your buck is Bitdefender Antivirus Plus as it’s fairly inexpensive and has an unlimited password manager, a file shredder and its own secure browser. How to choose the best Windows 10 antivirus for youĪs is the case with other types of software, you need to choose Windows 10 antivirus programs according to both your needs and budget. Read our full Trend Micro Antivirus+ Security review. You may also get a lot of false positives, or benign items flagged as suspicious, which may indicate that Trend Micro's malware-detection engine is a bit over tuned. The downsides are that you'll see a pretty heavy system slowdown during scans, so make sure to run them during off hours. For $40 per year for one PC, you get a gaming mode, a secure web browser for online banking, ransomware rollback and an email screener to guard against phishing attempts. Trend Micro does very well in some lab tests, but its Antivirus+ Security package is even more Spartan than ESET's among Windows 10 antivirus programs. Read our full Norton AntiVirus Plus review or save with our Norton coupon codes If you don't mind paying a premium price for an entry-level antivirus package, or if you were planning to pay for a VPN or password manager separately, you could do a lot worse. On the upside, Norton's track record at finding and defeating malware is second only to Kaspersky's. Other brands cover up to 10 PCs for that price. The next tier up, Norton 360 Standard, puts you in internet-security-suite territory by adding an unlimited VPN, webcam protection, dark-web scans for your personal information and 10GB of online storage. At $85 per year for a single PC though, it might be a bit expensive for some customers. Norton AntiVirus Plus protects one PC or Mac for a rather pricey $60 per year, but it does come with a two-way firewall, an unlimited password manager, backup software and 2GB of online storage. Norton sells nine different antivirus packages, but we'll focus on the two cheapest here. Read our full Kaspersky Anti-Virus review. Kaspersky Anti-Virus also has protection against " stalkerware" or spying programs that the company is rolling out across all its antivirus products. (You can pay extra to get unlimited versions of those.)īut Kaspersky Anti-Virus does give you exactly what you need: dedicated protection against encrypting ransomware, a filter against phishing emails, browser extensions to beef up web safety and a security scanner for your home Wi-Fi network. There are no parental controls, the password manager holds only 15 entries and the VPN service is limited to 300MB per day. Kaspersky Anti-Virus doesn't give many of you the extra bells and whistles you'll find with more expensive security suites. The company's entry-level package, Kaspersky Anti-Virus, covers up to three Windows PCs for $60 per year, or up to five for $80, though you'll often get half off for the first year. ![]() No other brand of antivirus software matches its nearly impeccable record in third-party lab tests. If you want the very best Windows 10 antivirus protection, Kaspersky Anti-Virus should be your first choice. As everyone’s security needs are different, we’ve also provided some tips on how to choose the best Windows 10 antivirus software for you. We’ve also examined how much they slow down your system and what you should be paying for the features on offer. We’ve taken a hard look at the best Windows 10 antivirus software to see how well they can protect your Windows PC. ![]() It’s worth noting though that these antivirus programs don't offer the same level of protection as the best internet security suites since only a few of them include a VPN or password manager. Besides protecting against malware and viruses, some of these programs come equipped with the ability to “rollback” files that have been encrypted by ransomware along with advanced protection to stop phishing emails, malicious links, fileless malware or boot-sector infections. Even though Windows Defender has improved significantly, you may still want some extra protection for your PC in addition to Microsoft’s own antivirus software that ships with Windows. ![]() Once trainers win 15 BP by participating in the Battle Tower theyll be able to exchange those points for a Focus Sash, in addition to multiple other items. Best answer The only place to get a Focus Sash in Pokemon X is for 48BP at the Battle Maison. If the holder has full HP and it is hit with a move that should knock it out, it will endure with 1 HP-but only once. The Focus Sash can also be obtained from the Battle Park in Pokémon BDSP after trainers earn the National Dex. ![]() The item then disappears.Īn item to be held by a Pokémon. If the holder has full HP, it will endure a potential KO attack with 1 HP. If it has full HP, the holder will endure one potential KO attack, leaving 1 HP.Īn item to be held by a Pokémon. Below the 2nd end but before def pbCallTitle :nodoc:, type DEBUG true and click save. At the top of the page, find eeze followed by end end. You will need to open it in something like NotePad You’ll see a bunch of code. The Focus Sash disappears after use.Īn item to be held by a Pokémon. Open up Reborn folder Click Scripts Find the file named Main. When this item is held by a Pokémon, if the Pokémon has full HP but is hit by an attack that would knock it out, this item prevents the holder from fainting and keeps it at 1HP. Black: Victini & ReshiramWhite: Victini & Zekrom.Pokémon Ranger & The Temple of the Sea!.One of these curious contenders is the enigmatic Galarian. Mystery Dungeon - Explorers of Time & Darkness Mon 28th Mar 2022 Pokémon have always had various ways of evolving into new beasties, and Pokémon Sword and Shield are no different.Mystery Dungeon: Blazing, Stormy & Light Adventure Squad.Pokémon Battle TrozeiPokémon Link: Battle. 9/9/2023 0 Comments Portuguese podengo wirehaired![]() The ultimate goal of the subreddit is to foster a better, science-based understanding of dogs among the general public, promote responsible dog ownership, help users build better relationships with their dogs, and provide a space to connect and discuss with others who have dogs and who are involved in various aspects of the dog hobby.Īdvice on this forum is absolutely not a substitute for professional advice from a certified behaviorist, trainer, lawyer, or medical professional. The purpose of /r/dogs is to provide an educational and supportive space for past, present, and future dog owners regarding a range of dog-related topics. Visit Doglime for more information about dog breeds temperament, personality, training, and puppies.Welcome to /r/dogs, the community for dog-lovers on Reddit! However, teach them not to trust every stranger they meet. ![]() After proper socialization, they can get along with strangers. Therefore, early socialization is necessary to avoid their wary nature around strangers. They tend to bark at every passing by strangers. Portuguese Podengo Pequeno is wary of strangers because of their protective nature towards their family. How Does Portuguese Podengo Pequeno Behave Around Strangers? Otherwise, Portuguese Podengo Pequeno are not known to be an aggressive dog. However, teasing them excessively and provoking can make them aggressive. They are friendly and gentle with everyone, even other canine pets. ![]() Portuguese Podengo Pequeno is not an aggressive dog breed. Image Source: _mauno What Makes Portuguese Podengo Pequeno Aggressive? However, they get well with older children who know how to handle and behave around dogs. They are lively and active, so interaction with small children should be supervised. Portuguese Podengo Pequeno makes a great companion for children, especially if they are raised together from an early age. Image Source: Instagram- Is Portuguese Podengo Pequeno Child-Friendly? Portuguese Podengo Pequeno Playing with a toy. Therefore, they will require a confident and firm training from its owner. Sometimes they can be stubborn and training can be a hard task to do. They will warn you by barking if there is anything odd going on in the area. Portuguese Podengo Pequeno is naturally protective of their family and surrounding, which makes them a great watchdog. They want to participate in family activities. Although they are small, Portuguese Podengo Pequeno is not a lap dog. They are a good entertainer who makes their family laugh all the time. Portuguese Podengo Pequeno has a silly personality. Personality of Portuguese Podengo Pequeno Some may suffer from separation anxiety if they have developed a strong bond with the owner. They need a lot of exercises and if they do not get enough work to do, they begin to show destructive behavior and can become anxious. They have a high tendency to chase small animals so while taking out for a walk or exercise, keep them on a leash.īehavior: Portuguese Podengo Pequeno craves for its owner attention so they tend to bark a lot when trying to get the attention. Portuguese Podengo Pequeno is a very active and tireless hunter that need lots of physical and mental exercise. They are always eager to please their owner, so training them is not a hard job to do. They make an excellent family pet due to this temperament. Portuguese Podengo Pequeno has a lively, playful, and charming temperament. Temperament of Portuguese Podengo Pequeno They are a very lively, alert, and smart little dog that hunts either separately or in a small pack. Their hair is either smooth or wirehaired. The ears are erect and the tail looks like a sickle. Portuguese Podengo Pequeno is a small- sized dog with a wedge-shaped head. Portuguese Podengo Pequeno uses sight, scent, and hearing to hunt its prey. They are bred as a hunting dog used to hunt rabbit and rodents. It is considered as a saperate breed by some purebreed dog registries including the American Kennel Club. ![]() The video tutorials were recorded on his computer. Later, he used a drawing application called SmoothDraw, and now uses a Wacom tablet to draw using ArtRage. Due to the demand, Khan decided to make his videos watchable on the Internet, so he published his content on YouTube. ![]() ![]() After a while, Khan's other cousins began to use his tutoring service. Starting in 2004, Salman "Sal" Khan began tutoring one of his cousins in mathematics on the Internet using a service called Yahoo! Doodle Images. As of February 2023, the Khan Academy channel on YouTube has 7.74 million subscribers and Khan Academy videos have been viewed over 2 billion times. All resources are available for free to users of the website and application.Īs of 2018, over 70 million people use Khan Academy, out of which 2.3 million students use it to prepare for the SAT. It has produced over 8,000 video lessons teaching a wide spectrum of academic subjects, originally focusing on mathematics and sciences. Its website also includes supplementary practice exercises and materials for educators. The organization produces short lessons in the form of videos. Its goal is creating a set of online tools that help educate students. Khan Academy is an American non-profit educational organization created in 2006 by Sal Khan. 9/8/2023 0 Comments Folx health coupon![]() ![]() This company is the most inevitable outcome of at least my career.Īt the same time, we have this unbelievably interesting moment where the technology is there. ![]() And then I have started other companies that secured funding, so I learned a lot of lessons that prepared me for this. I have had a long arc of a career in health care, and it has taken that long to understand how it all works, because it's so complicated. I started working with queer and trans kids in the streets of Boston right out of law school and saw up close how crappy the healthcare system was for our community. I’ve spent the last 30 years in health care. That's the less polite way of saying it, yeah.Īt some levels, this was the most obvious thing. What made you decide to pursue healthcare? It would be hard to start any company, but to build a queer and trans health care company requires fortitude…. That said, we're in a real zeitgeist moment. Proving there are enough of us to be worth some VCs time is a lot of work. There's a lot of stealth people actually in the older age ranges that just have never been comfortable sharing that identity in a public way. And the younger age groups, people who identify as queer is a rapidly growing demographic, because people are more comfortable identifying. But when are surveys done by queer and trans identified organizations, that number like jumps up to 20%. There is this idea that we're only like four and a half percent of the community. The next question is how many queer and trans folks are there to serve? This has always been a big question and there is a lot of shitty data out there. ![]() The first big hurdle is getting people to understand the magnitude of the pain. There are very few people in the VC community that are part of our community. View full post on Instagram Can you tell me a little bit more about the roadblocks you came across when creating Folx? When that happens, we will be including trans pediatrics-that’s in the distant future. In the very long range future, we want to open our own clinics so we can offer visits for things that really have to be in person. That's absolutely on the roadmap, probably later this year, or very early. And what about queer family planning services? Is that stuff going to be rolled out? They’ll be able to add also skin and hair specific supplements and medications, because as you know, there can be skin and hair complications from hormones, and sometimes they can make your skin go crazy. Folks can choose estrogen, they can add Spiro, they can add antiandrogens, progesterone, and more. It is already part of the basic HRT package. What medications are being covered now and what is being taken into consideration for future rollouts? I know a lot of queer folks take medications that are common within the trans community, but are not specifically for the trans community-like Sprionolactone, which is prescribed for acne, hypertension, and hormone-blocking. That did not line up 100%, but we got as close as we could. There are certain states that will license our clinicians more quickly, and the target states were based on where we saw the greatest need. We’re starting in 10 to 12 states, and then it'll roll out across the country over the course of the next six or seven months. So as hard as it is, we have also been blessed with enormous numbers of people who have stepped forward to say they are really eager to be part of this service. The queer community has a lot of caregivers, and a lot of people who have been waiting for something like this. The patient should be in control, and the clinician’s job is to support them by providing services that enable them to achieve their goals for care. Our ethos is also different from sort of traditional medical ethos-we’re not just going from patient centric, we're actually going for patient control. 9/8/2023 0 Comments Substitute for parsnips![]() Join 39,339+ readers of my weekly newsletter and I’ll send you a copy of my printable Ingredient Substitute ‘Cheat Sheet’ and my 102 page eCookbook…Ĭhicken broth from the carton,teduc d salt.I save all bits of leftover vegetables in a bowl covered in the freezer.Better soup.Lrarned this from my Granny.She made the best soup ever Roast th beef bones for soup rack & remove the marrow.Chopthis and return to kettle you are making soup bin.Summerin broth add bones.Add 1-2 large cans chop. We’ll turn you into a substitution pro in no time :) So maybe some roast eggplant or zucchini or mushrooms? Or saute some leafy veg like kale or spinach and use that instead. On a more general note, you could substitute any cooked veg or legumes. So you could substitute any of those vegetables.īroccoli is also under Green veg. Looking at out substitution guide above, broccoli appears in the Brassicas. Lets put this into practice with my Beautiful Broccoli with Creamy Tuna Sauce. Lettuce = radicchio = rocket (arugula) = baby spinach = baby kale = leafy herbs EXAMPLE: Beautiful Broccoli with Creamy Tuna Sauce Onions = celery = carrots = garlic Salad Veg Tomatoes = red bell peppers (capsicum) = eggplant (aubergine) = zucchini = mushrooms Aromatic Veg Zucchini = peas = green beans = broad beans = broccoli = asparagus Summer Veg Potato = sweet potato = parsnip = beets = turnip = celeriac = swede = rutabaga = carrots = mushrooms = zucchini = cauliflower Brassicasīroccoli = broccolini = cauliflower = cabbage = brussels sprouts = chinese broccoli Crunchy VegĬelery = snow peas = carrots = radish = kohlrabi = cabbage Green Veg Spinach = chard = silverbeet = collard greens = kale = cavolo nero = beet tops = cabbage = bok choy Root Veg Thyme = rosemary = sage = oregano = lemon grass = lemon thyme = kaffir lime leaves Leafy Veg Parsley = mint = coriander (cilantro) = basil = sorrel Woody Herbs So I’ve made a note to always include alternative veg ideas in my variations.Īnd I also thought it would be fun to empower you to try a little vegetable substitution on your own… The Ultimate Guide to Vegetable Substitutes Leafy Herbs I do use a lot of broccoli and cauliflower and kale in my recipes.īut just because a recipe calls for a certain veg, doesn’t mean you can’t use something else. Two of my long term Simple Meal Plans customers left comments saying they found my recipes lacking in vegetable variety. A few weeks ago I got some feedback that hurt. 9/8/2023 0 Comments Smoothmouse osx![]() Once you have updated and fixed your Mac that got stuck when installing macOS 11, run Disk Utility. Stuck on UEFI interactive shell with Mac OS X High Sierra VM.Programing mouse buttons for mac os sierra mac os x# When macOS Sierra was released we saw quite a few Wi-Fi-related issues, which we address in the guide: Common Problems After Installing macOS Sierra.Īsk Question Asked 3 years, 5 months ago.Thankfully, at least so far, we’re not seeing a repeat of major Wi-Fi issues. INSTALLATION Download the FortiClient VPN installer with the link below.Mac Installer Link Run the Installer from the downloaded location by double clicking on it. In Sierra, Apple has deprecated “IOHID”, the API SmoothMouse uses to move the mouse pointer.The recommended API called “CGEventPost” (a part of Quartz) is full of problems. We know this from our experience, because we used CGEventPost in SmoothMouse in 2012–2013 before switching to IOHID. The worst problem was performance.Programing mouse buttons for mac os sierra full# CGEventPost would make SmoothMouse skip movements when your computer was doing graphically intensive calculations. The second worst problem was that it didn’t work well with the applications that needed to take control of the mouse pointer. To our surprise, those weren’t only games, but also a plethora of professional applications like Ableton, Traktor, Cinema4D etc. Programing mouse buttons for mac os sierra full#.Programing mouse buttons for mac os sierra update#.Programing mouse buttons for mac os sierra install#.Programing mouse buttons for mac os sierra mac os x#.Programing mouse buttons for mac os sierra how to#. 9/8/2023 0 Comments Golf clash notebook wind appWhen calculating elevation, this is the downhill elevation, so a 20% lower landing spot is 20% downhill, 20% higher landing spot is minus 20% downhill. (3-(Accuracy x 0.02)) x (Max distance for club type / (Min distance for club type + ((club power-min distance for club type) x slider %) / (1 + Ball power modifier %) / (1 + downhill elevation %)īall power modifier is the % added to power: I posted this as a comment and have done a few times so I thought I'd make a post so it's easier to find.įull calculation to match Notebook/Caddie is: Imagine using 3.14 rather than Pi to calculate the area of a circle- you’d be close, but not right, and this is the same kind of principle here, so a bit of a fudge factor/different method is used to calculate the rings for some clubs. To add to my previous comment- I’ve consulted a more knowledgeable friend on this:īasically the wind/ring calculation is off for some clubs (noticeably for accurate long irons) and hazard/wedge clubs (which is why we have things like the EB rule for example), and so they need a fudge factor applied to them to make it work. B52 has 6 more yards so at max distance a shot will be in the air longer than if you used Grizzly, so will be more affected by the wind and needs more adjustment What I do know is that for clubs of the same type and accuracy (B52 and Grizzly being the perfect example), the numbers are different because club distance also plays a part. Even for clubs of the same type it’s not even necessarily true to say that a 50 accuracy Wood club is half as accurate as a 100 accuracy wood club but I digress.Īs to why you pull more for a B52 over a sniper, I’m not sure as to the actual mathematical reasons, but just put it down to the arbitrary factor I mentioned at the start that it’s just a relative concept, which is why starting to use the wind/ring method and learning about elevation is such a huge thing for your ability within the game as so many eyeball players will just assume a 100 accuracy means 1 ring = 1mph, which is obviously rarely the case. GolfClashTommy's "Video Guides For All Tours (2-11)" Post and his video Guide for 47 Shootouts post.Īccuracy is not a universal measure within the game but merely a relative factor for clubs of the same type. Or click the GUIDE flair to see all Guide posts. Looking for guides? Check out the GUIDE WIKI Please report any rule violations directly to the moderation team. Please post all clan recruiting and searching posts on the recruiting sub: /r/GolfClashClans This rule also applies to callouts for emoji spamming and similar unsportsmanlike behavior. It may not be a cheat, so please check the Known Issues page on the wiki. This can be done via the in-game settings menu within the Golf Clash app or via their support website. Please report any cheats or suspect cheaters directly to Playdemic. Self promotion should be thoughtful, limited and consistently well received by the community. This includes "title only" posts, "I'm quitting" posts, and other posts that won't generate discussion. Low effort content will be removed at the discretion of the moderation team. You can and will be banned without warning. ![]() No personal attacks, no excessive profanity, no threats of violence. Please follow the Rediquette rules don't be a jerk. Rediquette is just as important as golf etiquette. You're allowed to have an opinion, but you're not allowed to be a jerk about it. This includes the buying, selling, and trading of accounts or game items. Posting content that encourages, instructs, or asks about cheats, hacks, or other topics that go against the Golf Clash Terms of Service are bannable offenses and will be removed. No hacking, cheating or buying/selling accounts. All content must be related to Golf Clash or this subreddit. |
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